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M ,$D 0 LCV(T2-T1) =(p2V2-p1V1)/(g-1) T N 6' 2 f f f f f f  f f f f f f f f  f f#Vz >L   9  L > ,$D 0 :  0dj3>L   z CVDT R 2ffff ;  03F4   z CVDT R 2ffffRz B   <  B  ,$D 0 =  0-B   x CpDT R 2ffff >  0؝-*   x CpDT R 2ffffU ? 0- D G ,$D 0 -p(Vg-Vl)=-nRT b 2fffff, @ 0,c- f < ,$D 0 `Q=nL 2 f A 0e- K ,$D 0 tnL nRT  2 f$ B 0j- ~C ,$D 0 c nL  2 f C 0Х- ^ v,$D 0 $ -DngasRT -pDV+W5u 2fffffff. D 0d- J ,$D 0 " Qp=DH DU-W;`  2fffffffff&  E 0x- X},$D 0 DU=Q+W DU=Q+WR 2ffffj F 0~- |,$D 0  DH=Qp Q-W5u j 2fffff.H  0޽h ? ̙33``___PPT10j`+H#oDF[' = @B D[' = @BA?%,( < +O%,( < +D{' =%(D#' =%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?\CB#ppt_xBCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?dCB0-#ppt_h/2BCB#ppt_yB*Y3>B ppt_y<* D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(D@' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*! %(D' =-o6Bdissolve*<3<*! 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S_QYSRvI{e, gnid\zzlۏeQ{Q,vQ (W{Yvr`:N: T0, p, V0 (W{Qvr`:N: T, p, V zzl1u{YSeQ{Q,EesX[SO|(ۏeQ{-Nvzzl)ZPNR,Vdk{/fN~p[hV,EedkǏ z/fN~pǏ z, g: Q=0 W=pY(V2-V1) V1=V+V0 V2=V DV= -V0 W= -pYV0= -pV0= -nRT0  26X        'H  0޽h ? ̙33___PPT10g+D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*E%(D' =-6B%strips(downRight)*<3<*ED' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-o6Bdissolve*<3<*D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-o6Bdissolve*<3<* D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+p+0+$ ++0+$ +  @(    c $ $T<$  0 $ pV:NdkǏ z:NN~pǏ z,Ee g: DU=-W=nRT0=CV(T-T0) nRT0/CV=T-T0 T=T0+nRT0/CV=T0(1+nR/CV) T=T0(1+(Cp-CV)/CV) 5" Cp-CV=nR T=T0(1+g-1)=gT0 {-Nzzlv)n^:NT=gT0. Y: T0=298K SO|:NUSSP[RP[t`lSO, g=5/3 T=5/3298=497K 0   .~ ;# H  0޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+$ +  $(   N  c $`q$d|}<$  0 $ O4. [NyUSSP[RP[t`lSOlgNS_Rp, vQp[C=R,Bldk_v'`(? : g1id\t`lSO, CV=3/2R dQ=dU-dW=CVdT+pdV=CVdT+RT/VdV dQ/dT=CV+(RT/V)dV/dT 5" dQ/dT=C=R (~agN) 4" CV+RT/V(dV/dT)=R=3/2R+RT/V(dV/dT) -1/2R=RT/V(dV/dT) -1/2=TdlnV/dT -1/2dT/T=-1/2dlnT=dlnV yR: +"dlnV=-1/2+"dlnT lnV=-1/2lnT+K lnV+lnT1/2=K ln(VT1/2)=K VT1/2=K S_lSOlVT1/2=8^pev_Rpe, dk_vp[C=R.Y: &:)        H  0޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* +8+0+ $ +   t (  tb  $ c $$tk}<$  0 $ >O5. 1molUSSP[RP[t`lSO,N298K,2p0~(1)I{)nS; (2)~pS; (3)lp=10132.5V+bv_SSOyR P, BlTǏ zvQ,W,DUTDH? : (1)t`lSOI{)nǏ z DU=0; DH=0 Q=-W=nRTln(V2/V1)=1717.3 J (2) ~pǏ z: Q=0 g=5/3 g~pǏ ze z_: p1V1g=p2V2g p1=2p0 V1=12.226 dm3 V2=24.452 dm3 p2=p1V1g/V2g=0.63p0 T2=p2V2/nR=187.7K DU=CV(T2-T1)=3/2R(187.7-298)=-1375 J W=DU=-1375 J DH=Cp(T2-T1)=-2292 J (3) Blb: b=p1-10132.5V1=78770 p2=10132.5V2+78770=326530Pa=3.223p0 T2=p2V2/R=960.3K DU=CV DT=8260 J DH=CpDT=13767 J W=-+"pdV=-+"(10132.5V+78770)dV=-3240 J Q=DU-W=11500 J :2.  1   Dr    V\ H t 0޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-6B%strips(downRight)*<3<*$+8+0+$$ +    P (  Pr  P c $Dm"`P<$D  0 0 ^O6. {S^: C6H6(g)+3H2(g)=C6H12(g) (W125! NvDH? ]w:(W298K,1'YlS N: DcHm(H2,g)=-241.8kJ/mol; DcHm(C6H6,g)=-3169.5kJ/mol; DcHm(C6H12,g)=-3688.9kJ/mol. Tir(vp[:N: Cp,m(C6H6,g)=11.72+0.2469T; Cp,m(H2,g)=28.87; Cp,m(C6H12,g) =10.88+0.4017T : 1uir(vqppBlS^p: DrHm(298K)=DcHm(C6H6,g)+3DcHm(H2,g)-DcHm(C6H12,g) =-3169.5-3241.8+(-3688.9) =-206 kJ/mol DrCp,m=10.88+0.4017T-11.72-0.2469T-328.87 =-87.45+0.1548T  & 3V      $7BH P 0޽h ? ̙33___PPT10p.+(D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =-6B%strips(downRight)*<3<*P+8+0+P0 +  0Tt(  T< T c $"P<$D 0 " `1uW\ +Y[_: DrHm(T)=DrHm(298K)++"298TDrCp,mdT = -206000 - 87.45(398-298) +0.1548/2(3982-2982) = -209400 J/mol = -209.4 kJ/mol S^(W125! NvS^p:N-209.4 kJ/mol. $8$ $$$ZjH T 0޽h ? ̙33~___PPT10^.+_-FPD' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =-o6Bbox(out)*<3<*T+8+0+T" +) =5,(  ,  , c $l"P<$D  0 " O7. ё^\ GzzlO'lS >ep,(W298K,1*NhQ'YlS N,\1id\ё^\ v|+geQ5id\zzl-N,BlSO|vgؚ)nGS? ]w:zzl~b: N2:80%(V);O2:20%(V). Cp,m(O2)=Cp,m(N2)=29 J/K.mol; Cp,m(ZnO)=40 J/K.mol. DfHm(ZnO,298K)=-349 kJ/mol. : S^SO|:N~pSO|,S^phQ(uNSO|v)nGS.Y NpRf[_sǏ zBl{:D  -   5    4z 8  , 8M ,$D 0` , 0fԔ8 B , 0l"8( "1molZn,1molO2,4molN2 298K,1p0.# 2  ?z 0  , 0 E ,$D 0` , 0fԔ0 M , 0@<"@ -1molZnO,0.5molO2, 4molN2 T?, 1p0.. 2 z (   , ( ] ,$D  0lB  , <DԔ(   , 0 "   RDH=0. 2Dz `X(  , E `X,$D  0N p X   ,  X(` , 0fԔp X N , 0l"  N  .1molZnO,0.5molO2, 4molN2 298K, 1p0./ 2  N `p  , ` lB , <DԔ`p  , 0ܰ"` 8p  dDH1B 2z hp  , E h- ,$D  0lB , <DԔhp  , 04G:   xDH2 T 2H , 0޽h ? ̙33kc___PPT10C.+^D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-6B%strips(downRight)*<3<*,D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-6B%strips(downRight)*<3<*,D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-o6Bdissolve*<3<*,D' =%(D' =%(D3' =4@BB BB%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-o6Bdissolve*<3<*,D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* ,%(D' =-6B%strips(downRight)*<3<* ,D' =%(D' =%(DE' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<* ,%(D' =-6B%strips(downRight)*<3<* ,D' =%(D' =%(DA' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-}6B!strips(upRight)*<3<*,+8+0+,: +  p(  ph 0 c $:h <$  0 :  ZnOvubpsS:NdkS^p: DH1=DfHm(ZnO,298K)=-349000 J DH2=+"Cp(Nir)dT=+"Cp,m(ZnO)+0.5Cp,m(O2)+4Cp,m(N2) dT =40(T-298)+0.529(T-298)+429(T-298) =170.5(T-298) DH=DH1+ DH2=0 -349000+170.5(T-298)=0 T-298=349000/170.5=2047 T=2345 K dkS^vg~)nGS:N2345K  OQ   H p 0޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =-6B%strips(downRight)*<3<*0+8+0+0: +< $  h(  h h S <:p<$ 0 : HO8(uT[_l6R /ll (W298K 1p N b'll1 T/lS"l2 vmTlSOV1:V2=0.5:1 eQ695KQ gPSBRvS^hV0S^s^aT g80%v/lS"llS:N/ll3 T4ll4 0Ջ{eQ1mol/lS"lT S^hV-N>eQY\pϑ ]w298K Nv gsQpRf[pencY N(Cp,m= a+bT+cT2 ) )  d       h 6<:uR,$ 0 4> DfHm Cp,m a b103 c106 HCl(g) 92.31 28.47 1.81 1.547 H2O(g) 241.83 30.00 10.71 1.117 H2O(l) 285.85 75.312 J/K.mol O2(g) 25.52 13.4 4.27 Cl2(g) 31.71 10.1 4.04   25(#?& !2H h 0޽h ? ̙33___PPT10.*h+G^D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D@' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-o6Bbox(out)*<3<*hD' =%(D' =%(DF' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-u6Bdiamond(in)*<3<*h+p+0+h: ++0+h: +  xz(  xB x S ':R<$  0 : (Sf[S^_:N HCl (g) + 0.25 O2 (g) = 0.5 H2O (g) + 0.5 Cl2 (g) S^vqS:N DrHm(298K)  0.5(-241.83) (-92.31))  28.61 kJ/mol S^vp[]:N DrCp,m = -3.6+ 4.8110-3 T 1.8810-6 T2 1uW\ +Y[_ 659K NvS^qS:N DrHm(659K) = DrHm(298K)+ DrCp,m dT = 29.23 kJ/mol J     N     H x 0޽h ? ̙33___PPT10t.*+㓸D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*x%(D' =-6B%strips(downRight)*<3<*x+8+0+x: +.  :2(    c $(R<$  0 : \Sel1mol/lS"lS0.5mol'll N298KRp0R659Kvpϑ:N DH1= Qp = 0.5Cp,m(1)+ Cp,m(2) dT = 16.2 kJ HClvlSs:N80% EeeQ1molHCl(g) S^>eQvpϑ:N DH2= DrHm(659K)0.8= -23.38 kJ S^>eQvpϑNR(ueg\S^irN298KRp0R695K YYOvpϑMb/f1uS^hV O~sXvpϑ Q= DH2 DH1 = 7.18 kJ *  ( (  ( (8  ( ( (7 $  (  (  "J     H  0޽h ? ̙33___PPT10t.*+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+: +xW_L[e?wVZku ̠ X"@)/H՚aad, 胉}^B>l>`F7 ̍zufYƹ={?sws~ǟ(@tT\.gs{H=d&|iͭv]?۸GGk4@Ӑ*.1\T\36♞LA0jAdKg: |??he|7S $JŧQ]$ᄸJjVMkm  y'\@1@9pPP|0zd d Gـ43ǐ#?٣#&?Ed+`qg&q.3ʉ;\K(̽Oy`N6Sh".2)d46w  gS&peY|5K|&CO PP~R'twIb :7qϷWwZ'{{MՒTR:o;IvN#e+(wkh?פˣ`t"#s`bb51h-"ךZ~6⹼%6ZbK ^J3Ifmu?2/wɏ<Z1w~1H 2ZV=ThߍLCm52 ,oawwj*}?Ϛ6@a2K`΋o3Bsw4MmYz/saxjּZY|^Immx3303'VDX3OG¯G2ԥt42M2[3acI,W_6O:z7pVꏠl {4EG:mͦƋs(GFYe ] #E *OĀ,7]=M 8尅I-Tܣh:\85!ޢv| B(yA/-uQ׷ʖro1=+)VuOAFlI|Eƹg(LNb72'+W`cޤDK0~ڠ p Cf` f!?(g~lI4 Ab6!E~ y~/CO|q-(bm98:4vw< ON$r#ىHdX*̙ɂy6Nd Υg'QΤ3$kȟI(KF\P1Z|.,{(1Y,# +k'c=.]zIi}G(~OM<u5~Jن67]vEؗ v>\pc X1w6-@IG',e.Wj^Kl6wiyCzż%j(mQƶ_ydkGnFeMbܹ묎Ïb! 5 :)ѹ\>:eќ.?Buj> _c Sqh6ӳ|*H@=)vJEV'I_=S@gzJ OqO߂܊lB6 m@9DN &ǐCB>|wGA~A Cʽs]:+7`~ Z ?Y|Swz?O]M'bsX6JD&/$.˟f4-bf6jPߡzrPb~< }۝f//-O\p:2Rq﯎`{:2 5H@㗄UZ' zQ f)`+np㷵ǁ4Emo0H$02x/OnקN,OH1 o!S)&NJ,YA*ڷM' %|P=K)L#4g*qC0[QEq- uJgOu=݇-KkeNW,V_lBnQzփUѻevݎEd_d6lwb FH4**fL/EF5.[`F\_$39*WCܱBo9+帒a{ߡ -.dR;s|4O%I8s9@qs ~<|/[O[rtW ~}\AdMImx߅ 0-( s(>P$0? c&&Oh+'0 `h  PowerPoint ʾĸichemi29mMicrosoft PowerPointP@ @;@5XZKGg    --- @ !---- @ !!---- @ !<---- @ !S---- @ !h---- @ !y---- @ !---- @ !---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ !---- @ ! ---- @ ! ---- @ !#---- @ ! )---- @ !5---- @ ! =---- @ ! 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