ࡱ> C@AB ( / 0DTimes New Roman0z[ 0D[SOes New Roman0z[ 0 DwiSO_GB2312Roman0z[ 010DSymbol12Roman0z[ 0@DўSObol12Roman0z[ 0PDWingdings 3man0z[ 0@ .  @n?" dd@  @@`` xtL    %  0AA ff3f33@33<^ ʚ;3ʚ;g4?d?d z[ 0Lppp@ <4!d!dL 0<4ddddL 0<4BdBdL 0 80___PPT10 ZZ? % DGv{0&HH,{kQ DGv{B &00&0VSf[S^8^(WR`)nR`S NۏL, (WdkagN N, (uDG\OS^eTR$RncgeO, EeDGv{[NSf[Wyr+R͑. N. I{)nǏ zvDG: N\SO|~SNR`)nǏ z, N N\O g(uR: 5" dG= SdT+Vdp 4" dG=Vdp I{)nǏ zdT=0 DG=+"Vdp (1) NUO{USSO|I{)nǏ zvDGGWS(u(1)_Bl{.v0s7! A$               P ` ` ̙33` 333MMM` ff3333f` f` f` 3>?" dd@,|?" dd@   " @ ` n?" dd@   @@``PR    @ ` ` p>> n(    6/ P  :USQdkYkHrh7h_   0U   r8USQdkYkHre,g7h_ ,{N~ ,{ N~ ,{V~ ,{N~   0; ``  X*  0  `   Z*  0X `   Z*Z  Bd޽h ? ̙33  ؞!jg  p(  pr p S LS    H p 0޽h ? ̙33___PPT10i.Փ`P]++D=' = @B +  0 \(   x  c $U'h  '   c $V' L<$  0 ' B  s *3޽h ? ̙33___PPT10.+Q[D<' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* 8%(D' =-6B%strips(downRight)*<3<* 8D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* 8D%(D' =-6B%strips(downRight)*<3<* 8DD' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* D[%(D' =-6B%strips(downRight)*<3<* D[DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* [k%(D' =-6B%strips(downRight)*<3<* [kDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* k%(D' =-6B%strips(downRight)*<3<* kD\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* +8+0+ ' + XP@(    c $l<$  0  j1. t`lSOI{)nǏ z: DG=+"nRT/pdp=nRT+"dlnp DG = nRTln(p2/p1) = nRTln(V1/V2) (2) [gqt`lSOI{)nǏ zRvlQ_: WR=nRTln(p2/p1) DG =WR (3) N_fSǏ zvRZPR:N I{NSO| T^e1uvQ\0 [Z( $$$$$$$$$$$$ $$$   !B  s *3޽h ? ̙33 ___PPT10.+ TdD' = @B DG' = @BA?%,( < +O%,( < +D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %%(D' =-6B%strips(downRight)*<3<* %DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%:%(D' =-6B%strips(downRight)*<3<*%:DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*:[%(D' =-6B%strips(downRight)*<3<*:[D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\l%(D' =-6B%strips(downRight)*<3<*\lDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l%(D' =-6B%strips(downRight)*<3<*lDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+ +H zPH(  H H S `<$ 0  H&2. QZSO|I{)nǏ zvDG: DG =+"Vdp VQZSO|vSOySRvSS_\ VSƉ:N8^ϑ,Ee: DG =V(p2 p1) (QZSO|,I{)n) (4) [N[ElSO, bQSOySSvQZv(YSO|vSR_ؚe) RS\ir(vr`e zNeQ(1)_, BlvQyROS $$$#,,,,, 9     H H 0޽h ? ̙33n f ___PPT10F .++D ' = @B D ' = @BA?%,( < +O%,( < +D' =%(Dp' =%(DX' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*H %(D' =-6B+checkerboard(across)*<3<*H DX' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*H ;%(D' =-6B+checkerboard(across)*<3<*H ;DX' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*H;Z%(D' =-6B+checkerboard(across)*<3<*H;ZD' =%(D' =%(DX' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*H[%(D' =-6B+checkerboard(across)*<3<*H[+8+0+H +R `<*(  < < S ]<$  0  ``N. S)nǏ zvDG: S)nǏ zvSO|pRf[Qpe+B#style.visibility<*< @%(D' =-6B%strips(downRight)*<3<*< @D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<@O%(D' =-6B%strips(downRight)*<3<*<@ODR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<Ok%(D' =-6B%strips(downRight)*<3<*<OkDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<k|%(D' =-6B%strips(downRight)*<3<*<k|D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<|%(D' =-6B%strips(downRight)*<3<*<|+8+0+< + rjpL(  L L S |)  <$ 0  8p[N{USI{SS)nǏ z: dS=dQR/T=CpdT/T dS= Cp/TdT S(T)=S0(T1)++"Cp/TdT =S0++"CpdlnT =S0+Cpln(T2/T1) (Cp:N8^pe) (6) S0/fh` Nir(vĉ[q, T1/fh`)n^,Sgh_0R. \h_(6)NeQ(5)_yRS_S)nǏ zvDG. `x  (D         H L 0޽h ? ̙33___PPT10.+27DX' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*L %(D' =-6B)barn(outHorizontal)*<3<*L D' =%(D' =%(DV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*L-%(D' =-6B)barn(outHorizontal)*<3<*L-D ' =%(D ' =%(DV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*L-C%(D' =-6B)barn(outHorizontal)*<3<*L-CDV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*LCX%(D' =-6B)barn(outHorizontal)*<3<*LCXDV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*LX%(D' =-6B)barn(outHorizontal)*<3<*LXDV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*L%(D' =-6B)barn(outHorizontal)*<3<*LD' =%(D' =%(DV' =A@BBB*B0B%(D' =1:Bvisible*o3>+B#style.visibility<*L%(D' =-6B)barn(outHorizontal)*<3<*L+8+0+L +  D(     c $)te<$  0  tjO: 300K, 1molUSSP[RP[t`lSO~N N_1u10p00R1p0, ՋBlTǏ zvQ0W0 DU0DH0 DS0DFTDG ]w:300K, 10p0 Ndkir(vSm=126.1 J/k.mol. SO|~SvǏ z g: (1)I{)nS; (2)I{)nI{YS(1p0); (3)~pS1p0; (4)~p,I{YS(1p0)1p0.`(*2  B  s *3޽h ? ̙33 ___PPT10.+ TdD' = @B D=' = @BA?%,( < +O%,( < +D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Ej%(D' =-6B%strips(downRight)*<3<*EjDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*jt%(D' =-6B%strips(downRight)*<3<*jtD ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*u%(D' =-6B%strips(downRight)*<3<*uDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+ +%  p`(  `j ` S  )<<$ 0 ) l: (1) V/fI{)nǏ z, t`lSOvU, HS/f)n^vQpe, Ee g: DU=0 (dT=0,t`lSO) DH=0 (dT=0,t`lSO) W=nRTln(p2/p1)=8.314300ln0.1= -5743.1 J Q= -W= 5743.1 J (DU=0 Q=-W) DG=nRTln(p2/p1)=WR= 5743.1 J/mol DF= D(G pV)=DG D(pV) = DG= 5743.1 J/mol (pV=nRT=8^pe) DS=nRln(p1/p2)=8.314ln10 =19.14 J/K.molv7*    #  2 H ` 0޽h ? ̙33JB___PPT10".5}+mD' = @B Dy' = @BA?%,( < +O%,( < +D' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`&%(D' =-6B'blinds(horizontal)*<3<*`&D`' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`&<%(D' =-6B'blinds(horizontal)*<3<*`&<DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`<R%(D' =-6B'blinds(horizontal)*<3<*`<RD`' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`R~%(D' =-6B'blinds(horizontal)*<3<*`R~DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`~%(D' =-6B'blinds(horizontal)*<3<*`~D' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =-6B'blinds(horizontal)*<3<*`D`' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =-6B'blinds(horizontal)*<3<*`DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =-6B'blinds(horizontal)*<3<*`D`' =%(D' =%(DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`!%(D' =-6B'blinds(horizontal)*<3<*`!DT' =A@BBB B0B%(D' =1:Bvisible*o3>+B#style.visibility<*`!7%(D' =-6B'blinds(horizontal)*<3<*`!7+8+0+`) + (  V  c $)T<$  0 ) (2) VdkǏ zvY+g`NǏ z(1)v T, Ee@b gr`Qpev9eS+B#style.visibility<**2%(D' =-6B%strips(downRight)*<3<**2DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*2:%(D' =-6B%strips(downRight)*<3<*2:DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*:P%(D' =-6B%strips(downRight)*<3<*:PDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Pe%(D' =-6B%strips(downRight)*<3<*PeDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*e{%(D' =-6B%strips(downRight)*<3<*e{D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*{%(D' =-6B%strips(downRight)*<3<*{DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+) + xp(    c $Hu<$  0  >(3) HQ1ut`lSO~pSǏ ze z_BlT2: p11-gT1g= p21-gT2g g=5/3=1.667 (T2/T1)1.667=(p1/p2)-0.667=10-0.667=0.2153 T2/T1=0.398 T2=119.4 K DS=0 Q=0 (~pSǏ z) W=DU=CV(T2 T1) =3/2R(119.4 300) =-2252.3 J DU= 2252.3 J/mol}         " p{ $B  s *3޽h ? ̙33___PPT10.+ TdD2' = @B D' = @BA?%,( < +O%,( < +D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*9%(D' =-6B%strips(downRight)*<3<*9DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*9f%(D' =-6B%strips(downRight)*<3<*9fDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*f%(D' =-6B%strips(downRight)*<3<*fD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-6B%strips(downRight)*<3<*+8+0+ + VNh(  h h S Zi<$  0   DH=Cp(T2 T1)=5/2R(119.4 300) = 3753.8 J/mol Sm (119.4K) =Sm0+ DS=Sm0=126.1 J/K.mol DG=D(H TS)=DH D(TS) =DH (T2S2 T1S1)= DH Sm(T2 T1) = 3753.8 126.1(119.4 300) =19020 J/mol DF=DU Sm(T2 T1) =20521 J/mol zx   +         H h 0޽h ? ̙33"___PPT10.50P+E!:D' = @B DQ' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h7%(D' =-6B%strips(downRight)*<3<*h7D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h7c%(D' =-6B%strips(downRight)*<3<*h7cD ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*hcy%(D' =-6B%strips(downRight)*<3<*hcyDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*hy%(D' =-6B%strips(downRight)*<3<*hyDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B%strips(downRight)*<3<*hDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B%strips(downRight)*<3<*hD\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B%strips(downRight)*<3<*hDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-6B%strips(downRight)*<3<*h+8+0+h +  >(     c $LL<$  0  n (4) ~pǏ z: Q=0 W=DU=CV(T2 T1) W=-+"pYdV=-+"p2dV=-p2(V2 V1) = -p2V2+0.1p1V1 p2=0.1p1 =-RT2+0.1RT1=-R(T2 0.1300) -R(T2 0.1300)= CV(T2 T1) R(T2 0.1300)=1.5R(300 T2) ㉗_: T2=192K     6          B  s *3޽h ? ̙33___PPT10.+y[D<' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*  %(D' =-6B%strips(downRight)*<3<*  D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* >%(D' =-6B%strips(downRight)*<3<* >DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* >^%(D' =-6B%strips(downRight)*<3<* >^DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* ^%(D' =-6B%strips(downRight)*<3<* ^D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =-6B%strips(downRight)*<3<* +8+0+  +:& $F(  $ $ c $e<$  0  v DU=1.5R(192 300)= 1346.9 J/mol W= DU=1346.9 J DH=2.5R (192 300)= 2244.8 J/mol DS=Cp,mln(T2/T1)+Rln(p1/p2) =2.5Rln(192/300)+Rln10=9.868 J/K.mol S2=Sm+ DS=126.1+9.868=136.0 J/K.mol DG= D(H TS)= DH (T2S2 T1S1) = 2244.8 (192136 300126.1) =9473.2 J/mol DF= D(U TS)= DU (T2S2 T1S1) =10371.1 J/molPJ  ! -  p "()B $ s *3޽h ? ̙332*___PPT10 .+y[D' = @B De' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$"3%(D' =-6B%strips(downRight)*<3<*$"3D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$3T%(D' =-6B%strips(downRight)*<3<*$3TD\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$Tq%(D' =-6B%strips(downRight)*<3<*$TqDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$q%(D' =-6B%strips(downRight)*<3<*$qD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-6B%strips(downRight)*<3<*$D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-6B%strips(downRight)*<3<*$DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-6B%strips(downRight)*<3<*$DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-6B%strips(downRight)*<3<*$D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$3%(D' =-6B%strips(downRight)*<3<*$3DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$3J%(D' =-6B%strips(downRight)*<3<*$3J+8+0+$ + (X(  (  ( c $x8<<$  0  R N. vSvDG: 1. s^avS: s^avS:NI{)nI{SvSǏ z, Ee: DG=0 (s^avS) 2. ^s^avS: NSǏ z{ O: ]w298K N4lvp*=23.76mmHg, Ջ{298K, 1atm Nv4l}lS:N T)n TS Nvm`4lvDG? : dk:NN^s^avS, yr NRSǏ z: 9@!$   J    B ( s *3޽h ? ̙33jb___PPT10B.+ TdD' = @B D' = @BA?%,( < +O%,( < +D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*( %(D' =-6B%strips(downRight)*<3<*( DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*((%(D' =-6B%strips(downRight)*<3<*((DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*((9%(D' =-6B%strips(downRight)*<3<*((9D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*(:O%(D' =-6B%strips(downRight)*<3<*(:OD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*(P%(D' =-6B%strips(downRight)*<3<*(PD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*(%(D' =-6B%strips(downRight)*<3<*(+8+0+( + $,&(  , , c $7  <$  0 7  DG= DG1+ DG2+ DG3 =RTln(p2/p1) + 0 + Vm(H2O)(p2 p1) = 8585.6+1.766= 8583.8 J<0 5" DG<0, dkǏ z/fNSǏ z.b}s      *     P F (z  , :@` , 00z X  , 0X7 I7  H2O(g), 298K 760mmHg> 2 ` , 0 _  , 0(7 >  H2O(l), 298K 760mmHg> 2 ` , 0(  , 0`%7 A_ H2O(g), 298K 23.76mmHg> 2 ` , 0 u , 0W7 T H2O(l), 298K 23.76mmHg> 2 `B , 0Doe e `B , 0Do `B , 0DoX  `B  , 0DoX   !, 0`^7 P v  jDG. 2 ", 0(d7 _  DG2 T 2 #, 0p7    DG1 T 2 $, 047}2   DG3 T 2B , s *3޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-6B%strips(downRight)*<3<*,+8+0+,7 +Z H@@(  @ @ S 7   <$  0 7 V. Sf[S^vDG 1. 1uGv[IN_vcBl{: Sf[S^(WR`)n NۏL, R: DG=D(H TS)= DH T DS (7) 1uS^vDrHTDrSsSSBlQDG. S^vqSTqS(uϑplKm[0 DH N)n^SSe dk_S(uegBl{ N T)n^ NvS^vDG0} (($f3   H @ 0޽h ? ̙33___PPT10.+y[D2' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@ %(D' =-6B%strips(downRight)*<3<*@ D ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@,%(D' =-6B%strips(downRight)*<3<*@,DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@,F%(D' =-6B%strips(downRight)*<3<*@,FDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@F\%(D' =-6B%strips(downRight)*<3<*@F\DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@\l%(D' =-6B%strips(downRight)*<3<*@\lD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@l%(D' =-6B%strips(downRight)*<3<*@l+8+0+@7 + 0(  0T 0 c $x7<$  0 7 2. 1uub T^e1uBl{: [IN: 1u3z[US(ub1mol~STirvS^vDrGmy:NSTirvid\ub T^e1u, :N: DfGm. 3z[US(vDfGm=0 S^vDG DrGm=("ni DfGm,i)Nir ("ni DfGm,i)S^ir (8)R`s+s($$((((((((("( $,,,,,,$$2  B 0 s *3޽h ? ̙33`X___PPT108.+ TdD' = @B D' = @BA?%,( < +O%,( < +D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =-6B%strips(downRight)*<3<*0DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0K%(D' =-6B%strips(downRight)*<3<*0KD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0KY%(D' =-6B%strips(downRight)*<3<*0KYD\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0Y`%(D' =-6B%strips(downRight)*<3<*0Y`DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0`%(D' =-6B%strips(downRight)*<3<*0`+8+0+07 + 0PD(  P  P S ,,<$ 0 7 z 3. Gibbs-HelmholzlQ_: wSN*N)n^ NvDrGm BlvQ[)n^ NvDrGm  BlRNGibbs-HelmholzlQ_,00,,,,, ,,,,,,, H P 0޽h ? ̙33  ___PPT10d .5P,o+cD ' = @B D ' = @BA?%,( < +O%,( < +D' =%(D' =%(DF' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P$%(D' =-u6Bdiamond(in)*<3<*P$D' =%(D' =%(DF' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P$2%(D' =-u6Bdiamond(in)*<3<*P$2D' =%(D' =%(DF' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P2F%(D' =-u6Bdiamond(in)*<3<*P2F+8+0+P7 +# 2 * D(  D D S ,` i<$  0 , P gS^: A!B DrG=GB GA [(DG)/T]p= (GB/T)p (GA/T)p = SB ( SA) = DS (9) 5" DG= DH TDS I{)nǏ z 4" TDS = DG DH (10) \(10)_NeQ(9)_, S_: T [(DG)/T]p = DG DH (11)  xxx (,f8     l *vR Dv*R,$D  0f2 D 6Ԕ*2 Rf2 D 6Ԕv < H D c BZCxDEXF(AAԔ3t8.<A FQt}ZhBTf3?x@       "` YH D 0޽h ? ̙33 ___PPT10.+gmD' = @B DD' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D %(D' =-6B%strips(downRight)*<3<*D D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*DA%(D' =-6B%strips(downRight)*<3<*DADR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*DAX%(D' =-6B%strips(downRight)*<3<*DAXDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*DXp%(D' =-6B%strips(downRight)*<3<*DXpD\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Dp%(D' =-6B%strips(downRight)*<3<*DpDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-6B%strips(downRight)*<3<*DD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-6B%strips(downRight)*<3<*DDE' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-6B%strips(downRight)*<3<*DD;' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-w6Bdiamond(out)*<3<*D+8+0+D, +e!   4 (  4 4 c $X,L<$  0 , H g_R_: [(DG/T)/T] p= 1/T(DG/T)p+ DG( 1/T2) 1/T(DG/T)p= [(DG/T)/T]p+ DG/T2 T(DG/T)p= T2[(DG/T)/T]p+ DG 1u(11)_: T[(DG)/T]p= DG DH = T2[(DG/T)/T]p+ DG DG DH = T2[(DG/T)/T]p+ DGBvJ        $             pl 7 f2 4f7 2,$D 0f2 4 633Ԕ7  g2f2 4 633Ԕd f 4 c BCDE4FAAԔ %KDq* R( @    "`=? B 4 s *3޽h ? ̙33 ___PPT10.+]D' = @B DF' = @BA?%,( < +O%,( < +D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*40%(D' =-6B%strips(downRight)*<3<*40DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*40W%(D' =-6B%strips(downRight)*<3<*40WDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4W|%(D' =-6B%strips(downRight)*<3<*4W|D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4|%(D' =-6B%strips(downRight)*<3<*4|DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DQ' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DG' =4@BBB B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B'blinds(horizontal)*<3<*4D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4+8+0+4, + PX(  Xt X S 'w<$  0 , PDG DH = T2[(DG/T)/T]p+ DG T2[(DG/T)/T]p= DG DH DG tet_ [(DG/T)/T]p= DH/T2 (12) yR_: DG2/T2= DG1/T1+ DH(1/T2 1/T1) (13) (12)T(13)_GWy:NGibbs-HelmholzlQ_. L8 F$$$$ $$$$$$$ $$$$$$$f$( ((((( ($$f$$$$$$$$$$$$ $$$" H X 0޽h ? ̙33nf___PPT10F.5pZ +E!:D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X8%(D' =-6B%strips(downRight)*<3<*X8D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X8=%(D' =-6B%strips(downRight)*<3<*X8=DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X=]%(D' =-6B%strips(downRight)*<3<*X=]D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X]c%(D' =-6B%strips(downRight)*<3<*X]cDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Xc%(D' =-6B%strips(downRight)*<3<*XcD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =-6B%strips(downRight)*<3<*X+8+0+X' +# L D 8(  8 8 c $(u'3<$  0  HO: g NRS^: 2SO3(g, 1p0) D 2SO2(g,1p0)+ O2(g,1p0) ]w298Ke, S^vDrGm=1.400105 J/mol, DrHm=1.9656105 J/mol, S^vqS N)n^ SS, Bl(W600!e, dkS^vDrGm? : 1uG-HlQ_: DG2/T2= DG1/T1+ DH(1/T2 1/T1) DG2/873=140000/298+195600(1/873 1/298) = 35.36 DrGm(873K)=30869 J/mol k.   % @   *$B 8 s *3޽h ? ̙33xp___PPT10P.+ TdD' = @B D' = @BA?%,( < +O%,( < +D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8 3%(D' =-6B%strips(downRight)*<3<*8 3DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*83%(D' =-6B%strips(downRight)*<3<*83D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%%(D' =-6B%strips(downRight)*<3<*8%+8+0+8 +rd jT/|Pf9_jwTM&pZ In  _ ? IOh+'0H `h  第八节 G的计算 汪存信chem35mMicrosoft PowerPoint@pݞ P@@l,@0ZÑG:g     --- @ !%---- @ !+%---- @ !P---- @ !o---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !---- @ ! ---- @ ! ---- @ !&---- @ !6---- @ ! F---- @ ! Q---- @ ! ]---- @ ! i---- @ !u---- @ !---- @ !---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ ! ---- @ !---- @ ! ---- @ ! ,---- @ !8---- @ !G---- @ ! W---- @ !c---- @ !r---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !---- @ !'2---- @ !+Y---- @ !#---- @ !@---'@Symbol-.  2 ID>."System*-@Times New Roman-.  2 GM.-1_GB2312-. 2 ļdee.-՜.+,0   $, 4 &在屏幕上显示(武汉大学化学与环境科学学院XJA Times New Roman宋体楷体_GB2312Symbol黑体 Wingdings 3默认设计模板 G的计算第八节 G的计算 幻灯片 3 幻灯片 4 幻灯片 5 幻灯片 6 幻灯片 7 幻灯片 8 幻灯片 9 幻灯片 10 幻灯片 11 幻灯片 12 幻灯片 13 幻灯片 14 幻灯片 15 幻灯片 16 幻灯片 17 幻灯片 18 幻灯片 19 幻灯片 20 幻灯片 21 幻灯片 22 已用的字体演示文稿设计模板幻灯片标题_4Jchemchem  !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~      !"#$%'()*+,-./12345679:;<=>?DRoot EntrydO)Current User8SummaryInformation(&xPowerPoint Document(XJDocumentSummaryInformation80