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QZvSO|Sf[S^vT~RGWN~`:NhQ`, g: (mi*/p)T=Vm*(i) (DrGm0/p)T=(( RTlnK0)/p)T = RT(lnK0)/p)T=DrVm* 4" (lnK0)/p)T= DrVm*/RT (7) [NQZvS^: DrVm*>0 (lnK0)/p)T<0 MS[ckTS^ g)R; DrVm*<0 (lnK0)/p)T>0 XS[ckTS^ g)R; DrVm*=0 (lnK0)/p)T=0 9eSSRs^a NyR. ^w3v    @               H 4 0޽h ? ̙33|t___PPT10T.+ TdD' = @B D' = @BA?%,( < +O%,( < +D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4M%(D' =-6B%strips(downRight)*<3<*4MDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4Mj%(D' =-6B%strips(downRight)*<3<*4MjDj ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4j%(D' =-6B%strips(downRight)*<3<*4jDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4D ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =-6B%strips(downRight)*<3<*4DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4,%(D' =-6B%strips(downRight)*<3<*4,DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4,Q%(D' =-6B%strips(downRight)*<3<*4,QDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4Qv%(D' =-6B%strips(downRight)*<3<*4Qv+8+0+4 +. RJ8 (  8  8 c $xde{<$  0   PO: (W298.15K,1p0 N,wXv[^:N2.260g.cm3,ёRwv[^:N3.515g.cm3,ՋBl: (1) (W298.15K,1p0 N,&T1uwX6RYёRw; (2) (W298.15K N,RY'YvSRwXMbS:NёRw? : (1) 1upRf[penchg_: DfGm0(wX,298.15K)=0; DfGm0(ёRw,298.15K)=2.87 kJ.mol-1. S^ C(wX) = C(ёRw) (W298.15KT1p0 N: DrGm0(298.15K)=2.87-0=2.87kJ/mol>0 (WdkagN NS^ NckTۏL,EewX NSbёRw. (2) (WI{)nagN N g: (DrGm0/p)T=DrVm* DrGm(p) DrGm(p0)=+"DrVm*dp= DrVm*(p p0) N: DrGm(p)=0,dkewXNёRws^a. 4" DrGm(p0)=DrVm*(p p0) NeQ~agN:2 A + l            H 8 0޽h ? ̙33___PPT10.+ TdDN' = @B D ' = @BA?%,( < +O%,( < +D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8v%(D' =-6B%strips(downRight)*<3<*8vDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8D ' =%(D ' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8#%(D' =-6B%strips(downRight)*<3<*8#D' =%(Dl' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8#0%(D' =-6B%strips(downRight)*<3<*8#0DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*80G%(D' =-6B%strips(downRight)*<3<*80GDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8Gn%(D' =-6B%strips(downRight)*<3<*8GnDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8n%(D' =-6B%strips(downRight)*<3<*8nDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-6B%strips(downRight)*<3<*8+8+0+8 +   <Z(  <" < c $de{<$  0  -2870=(12.011/3.515-12.011/2.26)10-6(p-1-1325) ㉗_: p=1.51109Pa H"15000 atm. 傁(W298.15KagN N1uwX6RYёRw,@beRvSR\^'YN15000*N'YlS. N. `'`lSO[S^s^avq_T: ُ?Q@bv`'`lSO NNN/feCQ }, /fSO|-N@b g NSNSf[S^vbR. Y:[S^ CO+0.5O2=CO2 , N21\/fNy`'`lSO.hTgh-NveCQ },QNN/fNRlvS^v`'`lSO. `'`lSOvX[(W[S^s^ayRvq_TR$Ny`Q: (1) S^SO|v;`SR`[: S_SO|v;`SR`[e,ReQ`'`lSOOMNOS^~RvSR,ُyHe^NMNOS^SO|vSRvHe^/fN7hv,EeSN(uMRb@bN~v~g[dk\O T7hvRg.^#A'f2;3G1         H < 0޽h ? ̙33xp___PPT10P.+ TdD' = @B D' = @BA?%,( < +O%,( < +D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<1B%(D' =-6B%strips(downRight)*<3<*<1BDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<BT%(D' =-6B%strips(downRight)*<3<*<BTDR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<T%(D' =-6B%strips(downRight)*<3<*<TD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-6B%strips(downRight)*<3<*<D' =%(D^' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-6B%strips(downRight)*<3<*<DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-6B%strips(downRight)*<3<*<DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-6B%strips(downRight)*<3<*<D\' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-6B%strips(downRight)*<3<*<DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<^%(D' =-6B%strips(downRight)*<3<*<^+8+0+< +^  d\@(  @ @ c $DWd|{<$  0  $(2) SO|vSOyR`[: dkeReQ`'`lSOOOSO|v;`SGSؚ,FO[NSO|-NvS^~b ,vQRSKNTv^l g9eS,EeSf[s^a NOyR. FOS_S^SO|:N^t`lSOe,(WI{[agN NReQ`'`lSO gS9eSRS~Rv8^|pe,EeSO|vs^a_NSOyR.FO(WN,`Q N,SN NQ`'`lSOvq_T.& 3      H @ 0޽h ? ̙33___PPT10z.+y[D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@ C%(D' =-6B%strips(downRight)*<3<*@ CD' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@C%(D' =-6B%strips(downRight)*<3<*@C+8+0+@ +~   L2(  L L S ( <$D  0 ? hO: gTb(lS^: N2+ 3H2= 2NH3 (W748KT300p0 N,.l"lk cSf[ϑ|pekۏLmTv^OKNSuS^,S_0R31%vNH3.wYvmTirSOy~vRpeR+R:N:18%N2, 72%H2T10%v`'`lSO,ՋBlNH3vNs? : ]w(W~agN N,S^SO|vKg=0.5776. N2 + 3H2 = 2NH3 t=0: 1.0 3.0 0 s^a: 1-x 3-3x 2x n=4-2x  "   #d  %#H L 0޽h ? ̙33|___PPT10\.+fTD' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(D>' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*L%(D' =-m6Bbox(in)*<3<*L+8+0+L? +Z j b D (  D  D c $(de{<$  0   *  Kx=(2x/(4-2x))2(4-2x)/(1-x)(4-2x)3/33(1-x)3 =16/27x2(2-x)2/(1-x)4 1u~NH3vNs: 2x/(4-2x)=0.31 x=0.4733 NeQKxv{_Bl_: Kx=4.0198 Kf0=KxKg(p/p0)-2=4.01980.5776(300/1)-2 =2.5810-5 S^SO|-NReQ10%v`'`lSO: N2 + 3H2 = 2NH3 `'`lSO t=0: 0.18 0.72 0 0.1 s^a: 0.18-x 0.72-3x 2x n=1-2x Kx=Kf0/(Kg(p/p0)-2)=4.02 =[2x/(1-2x)]2[(1-2x)/(0.18-x)][(1-2x)3/(0.72-3x)3] tet_e z: x2(1-2x)2/[(0.18-x)(0.24-x)3]=27.13  "     '  6N 5,) C(H D 0޽h ? ̙33___PPT10p.+/]D' = @B D' = @BA?%,( < +O%,( < +D' =%(D' =%(DR' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-6B%strips(downRight)*<3<*D+8+0+D  +  H0(  H H c $tu {<$  0  `(uՋ]l㉗_: x=0.0984 S^s^ae,NH3v+Tϑ:N0.0984/(1-2*0.0984)=0.245,sS:N24.5%. N+T`'`lSOeNH3vNs31%,fS_SO|-N+T g`'`lSOeONH3vNsMNO. 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